Particle size control in dispersion polymerization

Control of Particle Size Distribution in Emulsion Co-polymerization Processes

A mid-course correction (MCC) policy has been shown as a practical approach to compensate the effects of the new disturbances on the final particle size distribution (PSD) in the emulsion polymerization process. However, the development of control model remains immature in the practical sense. In this paper, a control strategy to control the bi-modal particle size distribution in an emulsion co...

Dynamic Evolution of Droplet/Particle Size Distribution in Suspension Polymerization of Styrene

Inferential MIMO predictive control of the particle size distribution in emulsion polymerization

A new inferential 2-step multiple input/multiple output (MIMO) model predictive control (MPC) of the particle size distribution (PSD) in emulsion polymerization processes is proposed. The bulk-like model describing the PSD is used with the material balances of initiator, radicals, monomer and surfactant. The inferential 2-step control strategy uses two measurements available online (without del...

to control bead size distribution in suspension polymerization

suspension polymerization processes are significantly important in polymer bead formation. one of the important factors for bead size control in these processes is variation in surface tension. in this research, the prediction of optimum concentration of a surface active agent was investigated on the basis of the experimental surface tension diagrams. the experimental data show that the desired...

the effects of temperature, initiator and stabilizer on polymer particle size in suspension polymerization of styrene

in suspension polymerization, particle size distribution of polymer is the outcome of dynamic equilibrium between the break up and coalescence phenomena. the rates of break up and coalescence and consequently polymerization stability depend on several parameters, the most important of which are type and concentration of stabilizer. in this study, the effects of type and concentration of stabili...